Extraction of REE(III), U(VI), and Th(IV) from Nitric Acid Solutions with Diphenyl(dibutylcarbamoylmethyl)phosphine Oxide in the Presence of Quaternary Ammonium Bis[(trifluoromethyl)sulfonyl]imides
| Autor: | A. N. Turanov, A. N. Yarkevich, Vasilii K. Karandashev, V. A. Khvostikov |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Phosphine oxide
Sulfonyl chemistry.chemical_classification Trifluoromethyl Aqueous two-phase system 010402 general chemistry 010403 inorganic & nuclear chemistry 01 natural sciences 0104 chemical sciences chemistry.chemical_compound chemistry Nitric acid Ionic liquid Ammonium Physical and Theoretical Chemistry Imide Nuclear chemistry |
| Zdroj: | Radiochemistry. 61:694-699 |
| ISSN: | 1608-3288 1066-3622 |
| DOI: | 10.1134/s1066362219060092 |
| Popis: | The extraction of REE(III), U(VI), and Th(IV) from nitric acid solutions with solutions of diphenyl(dibutylcarbamoylmethyl)phosphine oxide considerably increases in the presence of ionic liquids with the bis[(trifluoromethyl)sulfonyl]imide anion and quaternary ammonium cations. The stoichiometry of the extractable complexes was determined. The influence of the HNO3 concentration in the aqueous phase, of the cation in the ionic liquid, and of the organic diluent on the efficiency of the extraction of REE(III), U(VI), and Th(IV) ions was examined. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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