Inherently dinuclear iridium(iii) meso architectures accessed by cyclometalation of calix[4]arene-based bis(aryltriazoles)

Autor:	Gennadij V. Latyshev, Kirill Ermolov, Stanislav I. Bezzubov, Alexander Gorbunov, Paulina Kalle, Ivan I Lentin, Vladimir Kovalev, Ivan Vatsouro
Rok vydání:	2021
Předmět:	Inorganic Chemistry chemistry Polymer chemistry medicine chemistry.chemical_element Iridium Hydrate Chloride medicine.drug
Zdroj:	Dalton Transactions. 50:16765-16769
ISSN:	1477-9234 1477-9226
Popis:	Conventional cyclometalation of calix[4]arene bis(aryltriazoles) with iridium(III) chloride hydrate leads to unique meso architectures in which the Ir2Cl2 core is cross-bound by two (C^N)2 ligands, which allows further replacement of the chloride bridges with ancillary ligands while maintaining the dinuclear structures of the complexes having independent or coupled iridium pairs.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::54c383b516fb32842a7c98256f14e6b9 https://doi.org/10.1039/d1dt03579g Zobrazit plný text záznamu