Discontinuous immittance due to a saddle node bifurcation

Autor:	B. Le Gorrec, Jean-Paul Diard, Claude Montella, Fabienne Berthier
Rok vydání:	1998
Předmět:	Nonlinear system Discontinuity (geotechnical engineering) Chemistry General Chemical Engineering Immittance Mathematical analysis Electrochemistry Saddle-node bifurcation Electrical impedance Bifurcation Sweep frequency response analysis Analytical Chemistry Dielectric spectroscopy
Zdroj:	Journal of Electroanalytical Chemistry. 458:231-240
ISSN:	1572-6657
DOI:	10.1016/s0022-0728(98)00359-3
Popis:	The Frumkin isotherm for the electrosorption reaction is S-shaped for the interaction parameter values lower than a critical level, leading to a hysteresis loop during steady-state studies. It is shown that isotherm branch switching phenomena can occur during the study of the electrosorption reaction by electrochemical impedance spectroscopy. Two- and three-part discontinuous impedance diagrams can be observed when the sinusoidal potential modulation spans the discontinuity potentials, depending on the frequency sweep direction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::54b31614ae5f56560cc806a109447a89 https://doi.org/10.1016/s0022-0728(98)00359-3 Zobrazit plný text záznamu Full Text from ScienceDirect