Three-body interaction effects in heterolytic hydrogen splitting by frustrated Lewis pairs

Autor:	Małgorzata M. Szczȩśniak, Grzegorz Chałasiński
Rok vydání:	2023
Předmět:	General Physics and Astronomy Physical and Theoretical Chemistry
Zdroj:	Physical Chemistry Chemical Physics. 25:9599-9606
ISSN:	1463-9084 1463-9076
Popis:	The reaction of heterolytic dihydrogen splitting by frustrated Lewis pairs P(R)3 and B(C6F5)3 (where R = t-butyl and 1-adamantene) is driven by strong three-body contributions which originate from the induction and charge transfer effects.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::54a4d0bffd424a606af8b50d0e10e4a8 https://doi.org/10.1039/d3cp00617d Zobrazit plný text záznamu