Surfaces and interfaces governing the OMVPE growth of APD-free GaP on AsH3-cleaned vicinal Si(100)

Autor: William E. McMahon, Emily L. Warren, Alan E. Kibbler, Ryan M. France, Andrew G. Norman, Robert C. Reedy, Jerry M. Olson, Adele C. Tamboli, Paul Stradins
Rok vydání: 2016
Předmět:
Zdroj: Journal of Crystal Growth. 452:235-239
ISSN: 0022-0248
DOI: 10.1016/j.jcrysgro.2016.05.014
Popis: Direct growth of GaP on Si enables the integration of III–V and Si optoelectronic devices for a wide variety of applications, and has therefore been the subject of much research for many decades. Most of this effort has been directed toward overcoming the two main technical challenges: 1) removing atmospheric oxygen and carbon contamination and 2) establishing the conditions needed for “APD-free” III–V epitaxy ( i.e ., without antiphase domains). We have developed an OMVPE process for APD-free GaP growth on Si which overcomes both challenges by using AsH 3 to clean and prepare the Si surface in situ at a relatively low temperature. This process is based upon a very brief “AsH 3 -cleaning” step which simultaneously removes atmospheric contamination (thereby eliminating the need for Si regrowth) and creates a single-domain As-terminated Si surface. Here we discuss the key process steps using results from a suite of analysis tools.
Databáze: OpenAIRE