Autor:	L. G. Lavrenova, S. V. Larionov, Liliya A. Sheludyakova, V. A. Varnek, Vladimir N. Ikorskii, V. L. Varand, O. G. Shakirova, Yu. G. Shvedenkov, T. A. Krieger
Rok vydání:	2000
Předmět:	Materials science Solid-state physics Ligand 1 2 4-Triazole Magnetic chemistry Inorganic Chemistry Crystallography chemistry.chemical_compound chemistry Spin crossover Phase composition Mössbauer spectroscopy Materials Chemistry Physical and Theoretical Chemistry Spectroscopy
Zdroj:	Journal of Structural Chemistry. 41:790-797
ISSN:	0022-4766
DOI:	10.1023/a:1004806101577
Popis:	The reaction of Fe(NO3)2, trz, and atrz in ethanol–water gave solid Fe(trz)3x(atrz)3-3x(NO3)2·H2O(x = 0.1, 0.2, 0.4, 0.8). The solids were investigated by magnetic chemistry, X-ray diffraction, photoelectron (DRS), IR, and Mossbauer spectroscopy methods. The individual Fe(trz)3(NO3)2 and Fe(atrz)3(NO3)2 as well as the solid phases exhibit a reversible spin crossover 1\(^1 A_1 \Leftrightarrow ^5 T_2 \), whose temperature and character depend on the phase composition. Due to this, Tc may be changed by introducing another ligand into the complex exhibiting a spin crossover effect.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::54779aa6139ca641ea92d8312f7c6173 https://doi.org/10.1023/a:1004806101577 Zobrazit plný text záznamu Full text from SpringerLink