Purification and characterization of phthalocyanines
| Autor: | Hans J. Wagner, Rafik O. Loutfy, Cheng-Kuo Hsiao |
|---|---|
| Rok vydání: | 1982 |
| Předmět: |
Zinc phthalocyanine
Materials science Magnesium Mechanical Engineering Inorganic chemistry chemistry.chemical_element law.invention chemistry.chemical_compound Lead phthalocyanine chemistry Metal free Mechanics of Materials law Copper phthalocyanine Phthalocyanine General Materials Science Sublimation (phase transition) Electron paramagnetic resonance |
| Zdroj: | Journal of Materials Science. 17:2781-2791 |
| ISSN: | 1573-4803 0022-2461 |
| DOI: | 10.1007/bf00644652 |
| Popis: | The technical details of a simple train sublimation (carrier gas) system for purification of organic materials are given and the refining procedure is described. A study of the effects of purification on metal free phthalocyanine (H2Pc), magnesium phthalocyanine (MgPc), copper phthalocyanine (CuPc), vanadyl phthalocyanine (VOPc), zinc phthalocyanine (ZnPc) and lead phthalocyanine (PbPc) was carried out by means of optical absorption, X-ray diffraction, electron paramagnetic resonance, sublimation behaviour and photovoltaic data. It was found that train sublimation improves the quality of the pigments considerably. Spectroscopic results indicate the presence of a second phase in the purified MgPc. |
| Databáze: | OpenAIRE |
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