Research in the chemistry of pyrazolidine XXIII. Study of the reaction of 3,5-dioxopyrazolidines with ?-nitrostyrene

Autor: A. S. Sopova, K. A. Sapozhnikova, B. L. Moldaver
Rok vydání: 1978
Předmět:
Zdroj: Chemistry of Heterocyclic Compounds. 14:776-778
ISSN: 1573-8353
0009-3122
DOI: 10.1007/bf00471651
Popis: Products of Michael condensation containing a 1-phenyl-2-nitroethyl residue in the 4 position of the heteroring are formed in high yields in the reaction of equimolar amounts of 4-methyl-,4-ethyl-, 4-isopropyl-, 4-butyl-, 4-isoamyl-, and 4-phenyl-1, 2-diphenyl-3,5-dioxopyrazolidines and 1,2-diphenyl-3,5-dioxopyrazolidine with β-nitrostyrene under basic catalysis conditions. 1,2-Diphenyl-3,5-dioxopyrazolidine adds two equivalents of β-nitrostyrene when a twofold excess of the latter is present.
Databáze: OpenAIRE