Research in the chemistry of pyrazolidine XXIII. Study of the reaction of 3,5-dioxopyrazolidines with ?-nitrostyrene
Autor: | A. S. Sopova, K. A. Sapozhnikova, B. L. Moldaver |
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Rok vydání: | 1978 |
Předmět: | |
Zdroj: | Chemistry of Heterocyclic Compounds. 14:776-778 |
ISSN: | 1573-8353 0009-3122 |
DOI: | 10.1007/bf00471651 |
Popis: | Products of Michael condensation containing a 1-phenyl-2-nitroethyl residue in the 4 position of the heteroring are formed in high yields in the reaction of equimolar amounts of 4-methyl-,4-ethyl-, 4-isopropyl-, 4-butyl-, 4-isoamyl-, and 4-phenyl-1, 2-diphenyl-3,5-dioxopyrazolidines and 1,2-diphenyl-3,5-dioxopyrazolidine with β-nitrostyrene under basic catalysis conditions. 1,2-Diphenyl-3,5-dioxopyrazolidine adds two equivalents of β-nitrostyrene when a twofold excess of the latter is present. |
Databáze: | OpenAIRE |
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