ChemInform Abstract: N-Bromosuccinimide-Mediated Radical Cyclization of 3-Arylallyl Azides: Synthesis of 3-Substituted Quinolines

Autor: Wei Yu, Wei-Xia Wang, Tianqi Zhang, Qingzhao Zhang, Zhan-Shan Li, Wei Zhang
Rok vydání: 2015
Předmět:
Zdroj: ChemInform. 46
ISSN: 0931-7597
DOI: 10.1002/chin.201522193
Popis: Under visible light irradiation of N-bromosuccinimide methyl 2-(azidomethyl)-3-aryl-propenoates and -acrylonitriles convert to the corresponding iminyl radicals which undergo intramolecular ortho attack on the aryl ring, affording methyl quinoline-3-carboxylates and 3-carbonitriles, respectively.
Databáze: OpenAIRE