ChemInform Abstract: N-Bromosuccinimide-Mediated Radical Cyclization of 3-Arylallyl Azides: Synthesis of 3-Substituted Quinolines
Autor: | Wei Yu, Wei-Xia Wang, Tianqi Zhang, Qingzhao Zhang, Zhan-Shan Li, Wei Zhang |
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Rok vydání: | 2015 |
Předmět: | |
Zdroj: | ChemInform. 46 |
ISSN: | 0931-7597 |
DOI: | 10.1002/chin.201522193 |
Popis: | Under visible light irradiation of N-bromosuccinimide methyl 2-(azidomethyl)-3-aryl-propenoates and -acrylonitriles convert to the corresponding iminyl radicals which undergo intramolecular ortho attack on the aryl ring, affording methyl quinoline-3-carboxylates and 3-carbonitriles, respectively. |
Databáze: | OpenAIRE |
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