Structure and Rearrangement Reactions of Bis(organosilyl)(organostannyl)hydroxylamines: A Joint Theoretical/Experimental Study
| Autor: | Thomas Labahn, Uwe Klingebiel, Hermann Stoll, Christina Ebker, Stefan Schmatz |
|---|---|
| Rok vydání: | 2002 |
| Předmět: |
Reaction mechanism
010405 organic chemistry Chemistry Organic Chemistry chemistry.chemical_element Crystal structure 010402 general chemistry Photochemistry 01 natural sciences Transition state 3. Good health 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Hydroxylamine Polymer chemistry Physical and Theoretical Chemistry Tin |
| Zdroj: | Organometallics. 22:490-498 |
| ISSN: | 1520-6041 0276-7333 |
| Popis: | O-Lithium-N,N-bis(tert-butyldimethylsilyl)hydroxylamide reacts with chlorotrimethylstannane to give N,O-bis(tert-butyldimethylsilyl)-N-(trimethylstannyl)hydroxylamine (1), the crystal structure of which is presented. The primarily formed N,N-bis(tert-butyldimethylsilyl)-O-(trimethylstannyl)hydroxylamine undergoes a dyotropic rearrangement. This reaction mechanism is corroborated by quantum-chemical calculations (B3LYP), partly employing an effective core potential for tin. The possibility for insertion of a stannyl group has been studied by quantum-chemical calculations. The transition states in the various rearrangement reactions of the bis(organylsilyl)stannylhydroxylamine system are discussed in detail. |
| Databáze: | OpenAIRE |
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