Synthesis of π-Extended Siloles Using Intramolecular Chain Hydrosilylation

Autor:	Takayuki Kawashima, Hidekazu Arii, Kenichi Nakabayashi, Kunio Mochida
Rok vydání:	2017
Předmět:	010405 organic chemistry Chemistry Hydrosilylation Organic Chemistry chemistry.chemical_element 010402 general chemistry Photochemistry 01 natural sciences Catalysis 0104 chemical sciences chemistry.chemical_compound Chain (algebraic topology) Metal free Intramolecular force Polymer chemistry Boron
Zdroj:	Synthesis. 49:4599-4605
ISSN:	1437-210X 0039-7881
Popis:	Intramolecular chain hydrosilylation afforded benzo- and naphtho-fused siloles in 20–81% yields from the corresponding hydrosilanes in the presence of a small amount of trityl tetrakis(pentafluorophenyl)borate as an initiator. This hydrosilylation can be applied for the synthesis of disiloles such as 1,5-disila-1,5-dihydro-s-indacene and naphthodisiloles.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5431936e8b2a63ab482c3f4deac83137 https://doi.org/10.1055/s-0036-1590911 Zobrazit plný text záznamu