Synthesis and characterization of microwave-hydrothermally derived Ba1−xSrxTiO3 powders
| Autor: | Sudhakar R. Sainkar, S.B. Deshpande, S.K. Date, Hari S. Potdar, Sudha V. Bhoraskar, Y.B Khollam |
|---|---|
| Rok vydání: | 2005 |
| Předmět: |
Strontium
Materials science Mechanical Engineering Potassium Inorganic chemistry chemistry.chemical_element Condensed Matter Physics Microstructure Oxalate Characterization (materials science) chemistry.chemical_compound chemistry Mechanics of Materials Barium titanate General Materials Science Stoichiometry Microwave |
| Zdroj: | Materials Letters. 59:293-296 |
| ISSN: | 0167-577X |
| DOI: | 10.1016/j.matlet.2004.10.006 |
| Popis: | Submicron-sized, spherical, stoichiometric strontium substituted barium titanate: Ba 0.75 Sr 0.25 TiO 3 (BST) powders are prepared by microwave-hydrothermal (MH) route under the MH conditions of 200 °C, 200 psi, and 30 min in strongly alkaline conditions (pH>12) using potassium titanyl oxalate (KTO) and nitrates of Ba and Sr as the starting precursors and KOH as the mineralizer. The characterization studies by XRD, XRF and SEM indicated that stoichiometric cubic BST powders ( a 0 =3.992 A) were obtained by adjusting MH conditions mentioned earlier and keeping the (Ba+Sr)/Ti ratio in starting solution slightly in excess (∼1.06). |
| Databáze: | OpenAIRE |
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