Electron impact studies—LXVII. The mass spectra of alkyl-1,3-dithianes

Autor:	John H. Bowie, P. Y. White
Rok vydání:	1972
Předmět:	chemistry.chemical_classification Chemistry Analytical chemistry Biochemistry Decomposition Ion Labelling Metastability Mass spectrum Molecular Medicine Physical chemistry Instrumentation Spectroscopy Electron ionization Alkyl
Zdroj:	Organic Mass Spectrometry. 6:317-324
ISSN:	1096-9888 0030-493X
DOI:	10.1002/oms.1210060310
Popis:	The mass spectra of 1,3-dithiane, 2-methyl- and 2,2-dimethyl-1,3-dithiane have been studied by 2H labelling and metastable defocusing. The various molecular ions eliminate S2H. to produce the ions [C4H7]+, [C5H9]+ and [C6H11]+ respectively, each of which scramble the hydrogens either before or accompanying further decomposition. Other processes are complex, but parallel those already reported for 2-aryl-1,3-dithianes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::54265927c3a5626215c4c884feea4909 https://doi.org/10.1002/oms.1210060310 Zobrazit plný text záznamu Plný text