A survey of the influence of EEDQ on efficient post-functionalization of an Anderson-type polyoxomolybdate towards construction of organic-inorganic hybrids
| Autor: | Hai-Kuan Yang, Yan-Kun Li, Xiao-Min Wang, Hong Zhao |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Steric effects Chemistry 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Organic molecules Colloid and Surface Chemistry Computational chemistry Electrophile Organic inorganic Cluster (physics) Surface modification 0210 nano-technology Spectroscopy Alkyl |
| Zdroj: | Colloids and Surfaces A: Physicochemical and Engineering Aspects. 538:711-719 |
| ISSN: | 0927-7757 |
| Popis: | In the present work, 2-ethoxy-1-ethoxycarbonyl-1,2-dihydroquinoline (EEDQ) was used as an effective coupling agent to design and synthesize a diversity of post-functionalized polyoxomolybdate (POM) hybrids based on an Anderson-type POM cluster and incorporating various organic molecules. Subsequently, the synthesized hybrids were characterized via various analytical and spectroscopic techniques including FT-IR spectroscopy, ESI–MS, 1H NMR spectroscopy, and elemental analysis. The present investigations revealed that different factors such as alkyl chain length, steric effect and electrophilicity had a profound effect on the post-functionalization of the Anderson-type POM cluster utilizing EEDQ as the coupling agent. By extensively investigating the effect of EEDQ on the efficient post-functionalization of an Anderson-type POM cluster, EEDQ can be more effectively utilized for post-functionalizing the POM clusters towards the future construction of various organic-inorganic hybrids. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect