Synthesis and crystal structure of hexakis(ε-caprolactam)lutetium(III) hexa(isothiocyanato)chromate(III) bis(ε-caprolactam) solvate
| Autor: | E. V. Cherkasova, A. V. Virovets, T. G. Cherkasova, Eugenia V. Peresypkina |
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| Rok vydání: | 2016 |
| Předmět: |
Aqueous solution
Chromate conversion coating Stereochemistry Materials Science (miscellaneous) Caprolactam Infrared spectroscopy chemistry.chemical_element Crystal structure Triclinic crystal system 010402 general chemistry 010403 inorganic & nuclear chemistry HEXA 01 natural sciences Lutetium 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Physical and Theoretical Chemistry |
| Zdroj: | Russian Journal of Inorganic Chemistry. 61:447-450 |
| ISSN: | 1531-8613 0036-0236 |
| Popis: | The reaction between Lu(NO3)3, K3[Cr(NCS)6], and e-caprolactam (e-C6H11NO) in an aqueous solution afforded complex [Lu(e-C6H11NO)6][Cr(NCS)6] · 2(e-C6H11NO) (I), the structure of which was determined by IR spectroscopy and X-ray diffraction. Crystals of I are triclinic, space group \(P\bar 1\), Z = 1, a = 12.1371(7) A, b = 12.2082(7) A, c = 12.7090(7) A, α = 67.2920(10)°, β = 87.9130(10)°, γ = 82.9410(10)°, V = 1723.86(17) A3, ρcalc = 1.426 g/cm3. |
| Databáze: | OpenAIRE |
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