Hypervalent Iodine(III) Reagent Promoted Rearrangement and Subsequent Oxidative Ring Cleavage of Cyclic 2,3-Epoxy-1-alcohol Derivatives

Autor: Satoshi Matsuda, Hiromichi Fujioka, Shinji Kitagaki, Ryoko Inoguchi, Kayoko Hata, Eri Fujii, Yasuyuki Kita
Rok vydání: 2006
Předmět:
Zdroj: ChemInform. 37
ISSN: 1522-2667
0931-7597
DOI: 10.1002/chin.200623054
Popis: The rearrangements of 2,3-epoxy alcohol derivatives were achieved using the hypervalent iodine(III) reagent, phenyliodine(III) b:is(trifluoroacetate) (PIFA). In the case of 2,3-epoxy alcohols subsequent oxidative ring cleavage occurred to give ω-formylalkanoic acids.
Databáze: OpenAIRE
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