Hypervalent Iodine(III) Reagent Promoted Rearrangement and Subsequent Oxidative Ring Cleavage of Cyclic 2,3-Epoxy-1-alcohol Derivatives
Autor: | Satoshi Matsuda, Hiromichi Fujioka, Shinji Kitagaki, Ryoko Inoguchi, Kayoko Hata, Eri Fujii, Yasuyuki Kita |
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Rok vydání: | 2006 |
Předmět: | |
Zdroj: | ChemInform. 37 |
ISSN: | 1522-2667 0931-7597 |
DOI: | 10.1002/chin.200623054 |
Popis: | The rearrangements of 2,3-epoxy alcohol derivatives were achieved using the hypervalent iodine(III) reagent, phenyliodine(III) b:is(trifluoroacetate) (PIFA). In the case of 2,3-epoxy alcohols subsequent oxidative ring cleavage occurred to give ω-formylalkanoic acids. |
Databáze: | OpenAIRE |
Externí odkaz: |
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