Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands: Synthesis, Structure, and Photophysical Properties

Autor:	Mikhail A. Kinzhalov, Svetlana A. Katkova, Ivan I. Eliseev, Alexander S. Mikherdov, E. V. Sokolova, Galina L. Starova
Rok vydání:	2021
Předmět:	Nitrile 010405 organic chemistry Chemistry Dimer Intermolecular force chemistry.chemical_element General Chemistry Nuclear magnetic resonance spectroscopy 010402 general chemistry Mass spectrometry 01 natural sciences 0104 chemical sciences Isocyanide ligands Crystal chemistry.chemical_compound Polymer chemistry Platinum
Zdroj:	Russian Journal of General Chemistry. 91:393-400
ISSN:	1608-3350 1070-3632
DOI:	10.1134/s1070363221030099
Popis:	A series of cyclometalated platinum(II) complexes with nitrile and isocyanide ligands (RCN and RNC; R = t-Bu, Bn, Ph) have been synthesized in 60–80% yields from the dimer [{Pt(ppy)Cl}2] (Hppy is 2-phenylpyridine) and the corresponding nitriles and isocyanides. The structure of the synthesized complexes was determined by mass spectrometry, IR and NMR spectroscopy, and X-ray diffraction. The contributions of different intermolecular interactions to the crystal packing were estimated by Hirshfeld surface analysis. Photophysical properties of the synthesized complexes in solution and solid state were studied.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::53eb7ae7268c7a69df802f81fea53113 https://doi.org/10.1134/s1070363221030099 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.