Interfacial Limitations of ALD-Grown Tin Oxide as an Electron Selective Layer in Perovskite-Based Solar Cells

Autor: Gayot, F., Bruhat, E., Manceau, M., De Vito, E., Mariolle, D., Cros, S.
Jazyk: angličtina
Rok vydání: 2022
Předmět:
DOI: 10.4229/wcpec-82022-2bo.7.3
Popis: 8th World Conference on Photovoltaic Energy Conversion; 237-240
Lower performances are usually recorded for perovskite and silicon/perovskite tandem solar cells that use tin oxide (SnO2) grown by Atomic Layer Deposition as an electron selective layer instead of solution-processed SnO2. This work attempts to determine possible causes for such limitations. A comparative study on chemical, electrical, optical and topographical properties of ALD-grown SnO2 and solution-processed SnO2 thin films and on their integration in perovskite-based solar cells is presented. This study points out the SnO2/perovskite interface as the main performance-limiting element. Specifically, a larger workfunction for ALD-grown SnO2 may create a potential barrier for electron extraction at PK interface.
Databáze: OpenAIRE