Hole burning with chelate complexes of quinizarin in alcohol glasses

Autor:	H. Wolfrum, D. Haarer, L. Kuemmerl
Rok vydání:	1992
Předmět:	Stereochemistry General Engineering Nuclear magnetic resonance spectroscopy Ion NMR spectra database chemistry.chemical_compound chemistry Molecule Physical chemistry Vibronic spectroscopy Methanol Physics::Chemical Physics Physical and Theoretical Chemistry Absorption (chemistry) Spectroscopy
Zdroj:	The Journal of Physical Chemistry. 96:10688-10693
ISSN:	1541-5740 0022-3654
DOI:	10.1021/j100205a022
Popis:	This paper reports about rare-earth metal ion (M 3+ ) chelate complexes of the dye molecule quinizarin which are well suited for hole-burning spectroscopy in alcohol glasses. Analyzing both, optical absorption and NMR spectra, information about the structure of the chelate complexes is obtained. A discussion of the possible photochemical reactions responsible for the hole-burning effect will be given. The measured line widths of various ion complexes in an ethanol/methanol glass show rather different values and temperature dependences and will be discussed in terms of ligand-to-metal energy-transfer processes
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::53cdf8f71672e3ae55b721ad987bbced https://doi.org/10.1021/j100205a022 Zobrazit plný text záznamu