Synthesis and spectral properties of iron(III) tetra- tert -butylphthalocyanine complexes
| Autor: | Anton D. Kosov, Tatiana V. Dubinina, Denis A. Pankratov, Larisa G. Tomilova, Ivan D. Burtsev, Yana B. Platonova |
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| Rok vydání: | 2017 |
| Předmět: |
biology
010405 organic chemistry Ligand General Chemistry 010402 general chemistry biology.organism_classification 01 natural sciences 0104 chemical sciences Catalysis law.invention chemistry.chemical_compound chemistry Oxidation state law Polymer chemistry Mössbauer spectroscopy polycyclic compounds Phthalocyanine Tetra Benzene Electron paramagnetic resonance |
| Zdroj: | Mendeleev Communications. 27:466-469 |
| ISSN: | 0959-9436 |
| Popis: | Two tetra-tert-butylphthalocyanine complexes of iron(III) were synthesized in high yields from the phthalocyanine ligand and iron(III) salts; the oxidation state of iron was confirmed by Mossbauer and EPR spectroscopy. The existence of an acid–base equilibrium during spectrophotometric titration was revealed. The ButPcFeCl complex catalyzed chlorination of benzene. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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