Pentacoordinate hydrochlorosilanes with lactamomethyl ligand

Autor:	M. G. Voronkov, V. A. Pestunovich, Natalya F. Lazareva, Svetlana V. Kirpichenko, Aleksander I. Albanov
Rok vydání:	2007
Předmět:	Reaction behavior Silicon Chemistry Ligand Stereochemistry Organic Chemistry Substituent chemistry.chemical_element Biochemistry Nmr data Inorganic Chemistry chemistry.chemical_compound Crystallography Intramolecular force Atom Materials Chemistry Chelation Physical and Theoretical Chemistry
Zdroj:	Journal of Organometallic Chemistry. 692:2160-2167
ISSN:	0022-328X
Popis:	The synthesis and reaction behavior of pentacoordinate hydrochlorosilanes LCH2SiRHCl (L- 2-piperidonyl ligand, R = Me, Ph, Bn) are described. The intramolecular O–Si and N–Si coordination is discussed on the basis of the NMR data. The strength of the O–Si coordinate bond is nearly the same for chelates 5, 6, 8 irrespective of the equatorial substituent R at the silicon atom. However, the nature of R substituent markedly affects the stability of the complexes with the N–Si intramolecular bond.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5356be1a85930164abbe40d76d2f2324 https://doi.org/10.1016/j.jorganchem.2007.01.035 Zobrazit plný text záznamu Full Text from ScienceDirect