Charge-separation reactions of N2O cations formed by low- and high-energy ionization

Autor:	John H. D. Eland, V. J. Murphy
Rok vydání:	1991
Předmět:	Chemistry Organic Chemistry Analytical chemistry Electron Photochemistry Spectral line Dissociation (chemistry) Analytical Chemistry Ion Dication Ionization Mass spectrum Physics::Chemical Physics Spectroscopy Excitation
Zdroj:	Rapid Communications in Mass Spectrometry. 5:221-225
ISSN:	1097-0231 0951-4198
DOI:	10.1002/rcm.1290050502
Popis:	Triple and quadruple coincidence charge-separation spectra of nitrous oxide ionized by single low-energy photons and by high-energy electrons are reported. Low-lying states of the molecular dication, which are populated at all energies, dissociate mainly into ion pairs by two-body reactions. The reaction producing N + +N+O + is weak at low excitation energy and may occur by a very fast secondary dissociation of intermediate dinitrogen ions
Databáze:	OpenAIRE
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