The Reaction Activity of Aromatic Carbonyl Compounds with Diphenylphosphine Oxide Studied by 31P NMR

Autor:	Yufen Zhao, Jinyun Zheng, Yujian Yu, Xiaomin Zhen, Xiangming Feng
Rok vydání:	2013
Předmět:	Phosphine oxide Organic Chemistry Substituent Carbon-13 NMR Diphenylphosphine oxide Biochemistry Medicinal chemistry Inorganic Chemistry Reaction rate chemistry.chemical_compound chemistry Hammett equation Proton NMR Organic chemistry Reactivity (chemistry)
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 188:1080-1087
ISSN:	1563-5325 1042-6507
DOI:	10.1080/10426507.2012.717137
Popis:	A series of α-hydroxyphosphine oxides were prepared by the reactions of diphenylphosphine oxide and aromatic carbonyl compounds and characterized by 1H NMR, 13C NMR, 31P NMR, FT-IR, ESI-MS, and HR-MS spectra. The reaction rates and experimental conditions of aromatic aldehydes and aromatic ketones were obviously different due to the activity of their carbonyls. The different substituents of the aromatic aldehydes affected the reaction rate too, and the quantitative reactivity of their substituent conformed to the Hammett equation. The results were confirmed by 31P NMR spectroscopy.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::534377e36f04b3a51cd3aa89d5308c8f https://doi.org/10.1080/10426507.2012.717137 Zobrazit plný text záznamu