ChemInform Abstract: THE SYNTHESIS AND REACTIONS OF 2,6-DIMETHYL-4-SILASPIRO(3,4)OCT-6-ENE

Autor:	Daiyo Terunuma, Noriyuki Shibuya, Hiroyuki Nohira
Rok vydání:	1982
Předmět:	Dimethyl acetylenedicarboxylate chemistry.chemical_compound chemistry Magnesium chemistry.chemical_element General Medicine Medicinal chemistry Ene reaction Isoprene Tetrahydrofuran
Zdroj:	Chemischer Informationsdienst. 13
ISSN:	0009-2975
DOI:	10.1002/chin.198242264
Popis:	A new silaspiro compound, i.e., 2,6-dimethyl-4-silaspiro[3.4]oct-6-ene, was synthesized by treating 1,1-dichloro-3-methyl-1-silacyclobutane with isoprene in the presence of magnesium in tetrahydrofuran. The reactions of the silaspiro compound with LiAlH4, H2PtCl6, dimethyl acetylenedicarboxylate in the presence of PdCl2(PPh3)2, and the Simmons-Smith agent were investigated.
Databáze:	OpenAIRE
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