Metathesis of renewable unsaturated fatty acid esters catalysed by a phoban-indenylidene ruthenium catalyst

Autor:	Robert P. Tooze, Roland Winde, Ronan Bellabarba, Ralf Karch, Grant S. Forman, Alexandra M. Z. Slawin
Rok vydání:	2006
Předmět:	Ethenolysis Methyl oleate Organic Chemistry Fatty acid ester Metathesis Biochemistry Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Materials Chemistry Ring-opening metathesis polymerisation Organic chemistry Physical and Theoretical Chemistry Carbene Unsaturated fatty acid
Zdroj:	Journal of Organometallic Chemistry. 691:5513-5516
ISSN:	0022-328X
Popis:	The phoban-indenylidene complex is a robust catalyst for self-metathesis and ethenolysis reactions of methyl oleate. The phoban-indenylidene catalyst was characterized by X-ray analysis, NMR and microanalysis and was used in various self-metathesis and ethenolysis of methyl oleate, giving rise to significantly higher end of run conversions compared to Grubbs 1st generation catalyst. These complexes are more stable and active than commercial Grubbs 1st generation catalyst, can be accessed from simple precursors and should give rise to more economical metathesis processes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::532666816879c9ba7d78d3966f0956f0 https://doi.org/10.1016/j.jorganchem.2006.06.021 Zobrazit plný text záznamu Full Text from ScienceDirect