Synthesis and X-ray powder diffraction data of 7-fluoro-2-exo-(2-methylpropen-1-yl)-2,3,4,5-tetrahydro-1,4-epoxybenzo[b]azepine

Autor:	Lina María Vélez Acosta, José A. Henao, Mario A. Macías, Alirio Palma
Rok vydání:	2013
Předmět:	chemistry.chemical_compound Crystallography Radiation Materials science chemistry X-ray General Materials Science Azepine Condensed Matter Physics Instrumentation Powder diffraction
Zdroj:	Powder Diffraction. 28:49-52
ISSN:	1945-7413 0885-7156
Popis:	The stereoselective synthesis of 7-fluoro-2-exo-(2-methylpropen-1-yl)-2,3,4,5-tetrahydro-1,4-epoxybenzo[b]azepine was developed by intramolecular 1,3-dipolar cycloaddition of the nitrone derived from the corresponding 2-allyl-4-fluoro-N-(3-methylbut-2-enyl)aniline. The X-ray powder diffraction (XRPD) pattern for the new compound was analyzed and found to crystallize in a monoclinic system with space group P21/m (No. 11) and refined unit-cell parameters a = 11.655(5) Å, b = 5.850(2) Å, c = 18.314(4) Å, β = 104.27(3) and V = 1210.1 (6) Å3.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::531d1a144ffb8265420ceb5170cf690d https://doi.org/10.1017/s0885715612000966 Zobrazit plný text záznamu