Overall kinetics of hydrogen peroxide formation by direct combination of H2 and O2 in a microreactor
| Autor: | Adeniyi Lawal, Yury Voloshin |
|---|---|
| Rok vydání: | 2010 |
| Předmět: |
Hydrogen
Autoxidation Applied Mathematics General Chemical Engineering chemistry.chemical_element General Chemistry Heterogeneous catalysis Decomposition Anthraquinone Industrial and Manufacturing Engineering Catalysis chemistry.chemical_compound Chemical engineering chemistry Organic chemistry Microreactor Hydrogen peroxide |
| Zdroj: | Chemical Engineering Science. 65:1028-1036 |
| ISSN: | 0009-2509 |
| DOI: | 10.1016/j.ces.2009.09.056 |
| Popis: | Direct combination (DC) of hydrogen and oxygen over a heterogeneous catalyst in a microreactor is a novel method of producing hydrogen peroxide with significant economic advantages over the currently dominant anthraquinone autoxidation method. A kinetic rate expression for this reaction is required for design and modeling of a microreactor for the DC process. Since the formation of H 2 O 2 by the DC process involves four simultaneous reactions (synthesis of H 2 O 2 , synthesis of water, reduction of H 2 O 2 by H 2 and decomposition of H 2 O 2 ), the overall rate expression must take into account each of these reactions. In this work, we describe a reactor model that involves the four component reactions as well as mass transfer effects. The model is verified by comparing the predicted reactor performance with experimental data. In addition to providing a tool for reactor design, the model also confirms important assumptions regarding the mechanism of DC reaction. |
| Databáze: | OpenAIRE |
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