Collisional relaxation of HCl (υ = 1) by selected polyatomic molecules

Autor:	R.D. Coombe, Donald Pilipovich, A. T. Pritt
Rok vydání:	1975
Předmět:	Chemistry Hydride Energy transfer Polyatomic ion General Physics and Astronomy Relaxation (physics) Molecule Electron Physical and Theoretical Chemistry Atomic physics Lone pair
Zdroj:	Chemical Physics Letters. 35:349-352
ISSN:	0009-2614
DOI:	10.1016/0009-2614(75)85618-1
Popis:	HCl (υ = 1) collisional relaxation rates have been measured for a number of polyatomic collision partners. The data suggest that for the polyatomic hydride (RH) species tested, the energy transfer proceeds via a vibration to vibration mechanism. The relaxation efficiencies of RCl species with lone pair or π electrons correlate well with the basicities of particular groups within the molecules.
Databáze:	OpenAIRE
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