Synthesis and highly effective purification of silver nanowires to enhance transmittance at low sheet resistance with simple polyol and scalable selective precipitation method
| Autor: | Jiunn-Yih Lee, Molla Bahiru Gebeyehu, Tolesa Fita Chala, Shao-Yen Chang, Chang-Mou Wu |
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| Rok vydání: | 2017 |
| Předmět: |
Materials science
Scanning electron microscope General Chemical Engineering Energy-dispersive X-ray spectroscopy Nanotechnology 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Indium tin oxide Silver nitrate chemistry.chemical_compound Chemical engineering chemistry X-ray photoelectron spectroscopy Transmittance 0210 nano-technology Sheet resistance Transparent conducting film |
| Zdroj: | RSC Advances. 7:16139-16148 |
| ISSN: | 2046-2069 |
| DOI: | 10.1039/c7ra00238f |
| Popis: | Networks of metal nanowires (NWs) have the highest performance of any solution-coatable material to replace expensive indium tin oxide (ITO) as the transparent conducting electrode material in next-generation devices. However, there is as yet no published process for producing NW films with an optoelectronic performance that exceeds that of ITO. Here, we examine a process for the synthesis and purification of uniform AgNWs that, when coated using a spin-coating technique to create a transparent conducting film, show properties that exceed those of ITO. The morphology AgNWs can be controlled by adjusting the concentration of silver nitrate (AgNO3) and [PVP] to [AgNO3] molar ratio. AgNWs with average diameters of 20 nm and aspect ratios >1000 were obtained by adding 30.5 mM of AgNO3 and 6 : 1 molar ratio of [PVP] to [AgNO3] in a silver nanowire synthesis, but these NWs were contaminated by some Ag nanoparticles. Selective precipitation was used to purify the NWs from nanoparticles, resulting in a transmittance improvement as large as 2%. The transmittance of the purified AgNW film was 97.5% at a sheet resistance of below 70 Ω sq−1. The synthesized and purified AgNWs were analyzed by field-emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), ultraviolet-visible-near-infrared (UV-Vis-NIR) spectroscopy and four-point-probe technique. |
| Databáze: | OpenAIRE |
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