Microwave detection of the primary ozonide of ethylene in the gas phase

Autor:	Frank J. Lovas, J. Zozom, Richard D. Suenram, Charles W. Gillies
Rok vydání:	1987
Předmět:	Ethylene Ozone General Physics and Astronomy chemistry.chemical_element Rotational transition Photochemistry Oxygen chemistry.chemical_compound Electric dipole moment chemistry Molecule Ozonide Rotational spectroscopy Physics::Chemical Physics Physical and Theoretical Chemistry
Zdroj:	Chemical Physics Letters. 140:64-70
ISSN:	0009-2614
DOI:	10.1016/0009-2614(87)80418-9
Popis:	The primary ozonide of ethylene has been observed and studied in the gas phase for the first time. A specially designed low-temperature absorption cell was employed in which the primary ozonide was prepared in situ by the low-temperature reaction of ozone with ethylene. An assignment of the rotational spectrum and electric dipole moment measurements have established the oxygen envelope conformation (C s symmetry) to the lowest-energy form for this elusive chemical species.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::52be95db8082056a209aff87ddc0d8f8 https://doi.org/10.1016/0009-2614(87)80418-9 Zobrazit plný text záznamu