Non-bonded interactions between proximate phenyl and polyflourophenyl rings? the regiospecific synthesis of the facial tetrafluorojanusene
| Autor: | Robert Filler, Gary L. Cantrell |
|---|---|
| Rok vydání: | 1987 |
| Předmět: |
chemistry.chemical_classification
Anthracene Stereochemistry Organic Chemistry Nuclear magnetic resonance spectroscopy medicine.disease_cause Biochemistry Cycloaddition Inorganic Chemistry chemistry.chemical_compound Polycyclic compound chemistry Polymer chemistry medicine Environmental Chemistry Moiety Fluorocarbon Physical and Theoretical Chemistry Ultraviolet |
| Zdroj: | Journal of Fluorine Chemistry. 36:407-419 |
| ISSN: | 0022-1139 |
| DOI: | 10.1016/s0022-1139(00)81982-x |
| Popis: | Cycloadditions of anthracenes to dibenzobarrelenes, with at least one C 6 F 4 moiety in either reactant, afford the janusenes 2 and 3 , in which phenyl and tetrafluorophenyl rings are disposed in a close facial relationship. Compound 3 , which is formed in a regiospecific manner, exhibits an ultraviolet spectrum that suggests a donor-acceptor interaction between the proximate -C 6 H 4 - and -C 6 F 4 - rings. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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