Generation and reactivity of bis(2,6-diethylphenyl)germanium(II)

Autor:	Satoru Masamune, Scott D. Collins, Shu Murakami, James T. Snow
Rok vydání:	1985
Předmět:	chemistry.chemical_classification Double bond Trimethylsilyl Organic Chemistry Photodissociation chemistry.chemical_element Germanium Photochemistry Biochemistry Adduct chemistry.chemical_compound chemistry Germane Drug Discovery Polymer chemistry Reactivity (chemistry) Triethylamine
Zdroj:	Tetrahedron Letters. 26:1281-1284
ISSN:	0040-4039
Popis:	The title intermediate ( 3a ) is produced on photolysis of hexakis(2,6-diethyl-phenyl)cyclotrigermane ( 1 ) or bis(2,6-diethylphenyl)bis(trimethylsilyl)germane ( 4 ) as evidenced by trapping experiments, and thermally dimerizes to tetrakis(2,6-diethyl-phenyl)digermene ( 2a ). Diarylgermylenes such as 3a do not form stable triethylamine adducts (e.g. 5a ) as has been previously reported.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::52a19840e0b8d0faef7952e2d9a55232 https://doi.org/10.1016/s0040-4039(00)94870-6 Zobrazit plný text záznamu