Two strategies of solar photo-Fenton at neutral pH for the simultaneous disinfection and removal of contaminants of emerging concern. Comparative assessment in raceway pond reactors
Autor: | J.A. Sánchez Pérez, P. Soriano-Molina, Patricia Plaza-Bolaños, S. Miralles-Cuevas, B. Esteban García |
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Rok vydání: | 2021 |
Předmět: |
02 engineering and technology
General Chemistry Treatment goals Contamination 010402 general chemistry 021001 nanoscience & nanotechnology Pulp and paper industry 01 natural sciences Catalysis 0104 chemical sciences Iron source Pilot plant Wastewater Environmental science Degradation (geology) Neutral ph 0210 nano-technology Raceway pond |
Zdroj: | Catalysis Today. 361:17-23 |
ISSN: | 0920-5861 |
DOI: | 10.1016/j.cattod.2019.11.028 |
Popis: | For the first time, two strategies of solar photo-Fenton at neutral pH (with FeSO4 and Fe3+-EDDS) are techno-economically assessed. With the target of simultaneous wastewater disinfection and removal of contaminants of emerging concern (CECs), a cost estimation ranging from 0.13 to 0.49 €/m3 as a function of the treatment goal is presented. To this end, the effects of liquid depth (5, 10 and 15 cm) and the iron species were studied at lab-scale. Afterwards, the feasibility of both operating strategies was evaluated and validated outdoors at pilot plant scale in low-cost raceway pond reactors. For the joint-removal of bacteria and CECs, the use of FeSO4 as iron source was cheaper than Fe3+-EDDS. However, it is important to highlight that although bacterial inactivation reached > 3 log, only around 35 % of CEC degradation was achieved with FeSO4, while more than 80 % CEC load was removed with Fe3+-EDDS. |
Databáze: | OpenAIRE |
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