Mechanism of Preparing White Electrophoretic Composite Spherical Particles by Precipitation Polymerization

Autor: 冯宇光 Feng Yu-guang, 黄世华 Huang Shi-hua, 滕枫 Teng Feng
Rok vydání: 2011
Předmět:
Zdroj: Chinese Journal of Liquid Crystals and Displays. 26:285-295
ISSN: 1007-2780
DOI: 10.3788/yjyxs20112603.0285
Popis: Under specific property of titanium dioxide and 4-vinylpyridine,titanium dioxide multi-core and poly(divinyl-benzene-styrene-4-vinyl pyridine) shell hybrid composite spherical and smooth particles were prepared in methanol by precipitation polymerization.DSC and TG had detected polymerizing effect,structure unit of polymer was confirmed by FT-IR,and SEM took photographs of composite microsphere.As a result,the stable spherical and smooth particles were obtained.The corresponding mechanism was confirmed by SEM photographs and changing some parameters of core/shell microspheres prepared in a series of methods.The dispersing order and amount of 4-vinylpyridine dominated the mechanism of forming composite spherical particle.Then,the electrophoretic property of the composite particle was verified with a quaternary ammonium salt combined with hydrocarbon bromide and pyridyl covered on the surface of microsphere prepared in methanol by precipitation polymerization.
Databáze: OpenAIRE