Bifurcations - a possibility to generalize the thermodynamic description of phase diagrams of two-component fluids

Autor:	L. Z. Boshkov
Rok vydání:	1992
Předmět:	Maxima and minima Formalism (philosophy of mathematics) Phase transition Thermodynamic state General Chemical Engineering Critical phenomena Binary number Statistical physics Maxima Phase diagram Mathematics
Zdroj:	Berichte der Bunsengesellschaft für physikalische Chemie. 96:940-943
ISSN:	0005-9021
DOI:	10.1002/bbpc.19920960716
Popis:	A new thermodynamic formalism has been developed for the analysis of the phase behaviour of two-component fluids. Azeotropy and critical pressure maxima or minima in binary fluids have been interpreted as bifurcations of two-phase equilibria and critical points, respectively. The analogous approach has been applied to some boundary states: hypercritical and isolated critical points, critical pressure step-points. The thermodynamic conditions of these states have been derived for the first time by a uniform way.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::52198b41c7e0d9b52ede906c3b43b7ed https://doi.org/10.1002/bbpc.19920960716 Zobrazit plný text záznamu Plný text