Dispersive kinetics in early events of peptide folding

Autor: Andrzej Plonka
Rok vydání: 2000
Předmět:
Zdroj: Chemical Physics Letters. 328:124-128
ISSN: 0009-2614
DOI: 10.1016/s0009-2614(00)00921-0
Popis: The stretched exponential (SE) and the power law (PL), fitting equally well the disulfide recombination of a de-novo peptide, differ markedly in estimation of thiyl radical population. This leads to quite different lifetime distribution functions encompassing about 20% (ES) or 70% (PL) of the radicals. For inhomogeneous recombination kinetics, the interpretation of the PL in terms of superposition of first-order decays is compared with that in terms of superposition of second-order decays.
Databáze: OpenAIRE