Novel quaternary ammonium salt-containing polyamines from the Agelenopsis aperta funnel-web spider

Autor:	Paul R. Kelbaugh, Kenneth J. Rosnack, James T. Forman, Robert A. Volkmann, Nicholas A. Saccomano, V. John Jasys, Deane M. Nason, Phillips Douglas, Justin G. Stroh
Rok vydání:	1992
Předmět:	chemistry.chemical_classification Spider biology Stereochemistry Organic Chemistry Total synthesis Salt (chemistry) Nuclear magnetic resonance spectroscopy Carbon-13 NMR Mass spectrometry Agelenopsis aperta biology.organism_classification chemistry.chemical_compound chemistry Ammonium
Zdroj:	The Journal of Organic Chemistry. 57:1814-1820
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo00032a039
Popis:	Two novel hydroxylamine-containing acylpolyamines, Agel 489a and Agel 505a, each bearing a terminal quaternary ammonium salt, were isolated from the venom of Agelenopsis aperta, a funnel-web spider found throughout the western United States. Published structures for these compounds were not consistent with our spectral data. On the basis of fast-atom bombardment (FAB) mass spectrometry and 1 H and 13 C NMR spectra, novel structures for Agel 489a and 505a are proposed. These structural assignments are confirmed by the total synthesis of Agel 489a
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::51e80b227014be2e920ea85f5a8e921f https://doi.org/10.1021/jo00032a039 Zobrazit plný text záznamu