Short and stereodivergent syntheses of (−)-5-epi-tashiromine and (−)-tashiromine and the formal synthesis of (−)-isoretronecanol and (−)-trachelanthamidine

Autor:	Mukund G. Kulkarni, Shashikant B. Bhorkade, Kishor B. Gavhane
Rok vydání:	2015
Předmět:	Chemistry Stereochemistry Organic Chemistry Vinyl ether Catalysis Inorganic Chemistry Isoretronecanol Formal synthesis Yield (chemistry) medicine Organic chemistry Physical and Theoretical Chemistry Trachelanthamidine Tashiromine medicine.drug
Zdroj:	Tetrahedron: Asymmetry. 26:746-750
ISSN:	0957-4166
DOI:	10.1016/j.tetasy.2015.05.011
Popis:	A successful application of the Wittig-olefination–Claisen rearrangement protocol gave the allyl vinyl ether 12 , which was efficiently converted into (−)-tashiromine alkaloids in a short sequence with high overall yield.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::51e618ec41ff9982839893435807f896 https://doi.org/10.1016/j.tetasy.2015.05.011 Zobrazit plný text záznamu Full Text from ScienceDirect