Synthesis, structural characterization and variable temperature electrical conductivity of a pentanuclear Pd(II)dithiolato complex

Autor:	Vinayak B. Kamble, Arnab Chatterjee, Arghya Dutta, Tathagata Sarkar, Shubhamoy Chowdhury, Rajarshi Ghosh
Rok vydání:	2021
Předmět:	Inorganic Chemistry Metal Crystallography Materials science Electrical resistivity and conductivity visual_art Materials Chemistry visual_art.visual_art_medium Physical and Theoretical Chemistry Characterization (materials science)
Zdroj:	Inorganic Chemistry Communications. 133:108889
ISSN:	1387-7003
Popis:	The sulphur bridged pentanuclear Pd(II) complex [Pd5(L)6] (1) (LH2 = benzene-1,2-dithiol) has been synthesized and X-ray crystallographically characterized. Each of the five metal centers in 1 are found to be in distorted square planar geometry. At room temperature in the solid-state 1 is found to conduct electricity. On increasing temperature, the electrical conductivity rises exponentially. From theoretical calculations electrical conductivity of 1 is found to behave in the range from metallic to semi conductor-like behavior.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::51c862479517d58ec98109ac95c5db1d https://doi.org/10.1016/j.inoche.2021.108889 Zobrazit plný text záznamu Full Text from ScienceDirect