Autor: |
Vinayak B. Kamble, Arnab Chatterjee, Arghya Dutta, Tathagata Sarkar, Shubhamoy Chowdhury, Rajarshi Ghosh |
Rok vydání: |
2021 |
Předmět: |
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Zdroj: |
Inorganic Chemistry Communications. 133:108889 |
ISSN: |
1387-7003 |
Popis: |
The sulphur bridged pentanuclear Pd(II) complex [Pd5(L)6] (1) (LH2 = benzene-1,2-dithiol) has been synthesized and X-ray crystallographically characterized. Each of the five metal centers in 1 are found to be in distorted square planar geometry. At room temperature in the solid-state 1 is found to conduct electricity. On increasing temperature, the electrical conductivity rises exponentially. From theoretical calculations electrical conductivity of 1 is found to behave in the range from metallic to semi conductor-like behavior. |
Databáze: |
OpenAIRE |
Externí odkaz: |
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