Polymeric transition metal complexes of 1,4-bis- (4-pyridylsulfenylmethyl)benzene and of its 2-pyridyl analogue

Autor:	Stephan Menzer, David J. Williams, Zeno Atherton, David M.L. Goodgame
Rok vydání:	1998
Předmět:	Denticity chemistry.chemical_element Photochemistry Inorganic Chemistry Metal chemistry.chemical_compound Oxygen atom chemistry Transition metal visual_art Polymer chemistry Materials Chemistry visual_art.visual_art_medium Chelation Physical and Theoretical Chemistry Benzene Cobalt
Zdroj:	Polyhedron. 18:273-279
ISSN:	0277-5387
DOI:	10.1016/s0277-5387(98)00295-2
Popis:	The preparations are reported of a range of complexes of MnII, CoII, NiII and CuII with 1,4-bis- (4-pyridylsulfenylmethyl)benzene (B4PSB) and of complexes of CoII, NiII and CuII with the 2-pyridyl analogue (B2PSB), together with relevant spectroscopic data. X-Ray crystallographic studies on Co (B2PSB) (NO3)2 show the presence of a chain structure in which five-coordinate cobalt centers are linked by bridging (B2PSB) ligands, with the remaining coordination sites about each metal atom being occupied by one very asymmetrically chelating nitrate group and an oxygen atom of a unidentate nitrate.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::51c84566dd711f850925e063d8ab3d8a https://doi.org/10.1016/s0277-5387(98)00295-2 Zobrazit plný text záznamu Full Text from ScienceDirect