Porous organic polymers as metal free heterogeneous organocatalysts

Autor:	Christian V. Stevens, Pascal Van Der Voort, Maarten Debruyne, Veronique Van Speybroeck
Rok vydání:	2021
Předmět:	chemistry.chemical_classification Green chemistry Materials science One-pot synthesis Nanotechnology Polymer Heterogeneous catalysis Pollution Conjugated microporous polymer Catalysis chemistry Metal free Environmental Chemistry Porosity
Zdroj:	Green Chemistry. 23:7361-7434
ISSN:	1463-9270 1463-9262
DOI:	10.1039/d1gc02319e
Popis:	Efficient catalysis is essential from a green chemistry perspective. Porous organic polymers (POPs) have recently emerged as highly effective materials for catalytic applications. POPs possess controllable compositions and functionalities, high surface areas and can be very stable. In this review we focus on the application of POPs as metal free heterogeneous organocatalysts, a booming field in green chemistry. Acid, base, combined acid–base and hydrogen bonding catalysis are addressed. In addition, chiral catalysis and CO2 utilization with POPs are discussed. The aim is to provide a comprehensive overview of the field, exploring all different types of POPs as metal free catalysts. Special attention is given to the synthesis conditions to provide the reader with more insight into the construction of these types of materials.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::51c0b8f96a145bb9fe73c2c3fa78d4dc https://doi.org/10.1039/d1gc02319e Zobrazit plný text záznamu