Oxidation of isosafrole by sodium hypochlorite catalysed by manganese porphyrins: Unusual competition between epoxidation and O-dealkylation

Autor:	Cecilia Querci, Luisella Bocchio Chiavetto, Gianfranco Guglielmetti, Marco Ricci
Rok vydání:	1996
Předmět:	O dealkylation media_common.quotation_subject Organic Chemistry chemistry.chemical_element Ether Manganese Biochemistry Competition (biology) Isoeugenol chemistry.chemical_compound chemistry Isosafrole Sodium hypochlorite Drug Discovery Moiety Organic chemistry media_common
Zdroj:	Tetrahedron Letters. 37:1091-1094
ISSN:	0040-4039
DOI:	10.1016/0040-4039(95)02312-7
Popis:	isosafrole (1a) and isoeugenol methyl ether (1b), two closely related substrates, behave very differently when subjected to manganese porphyrins catalysed epoxidation by sodium hypochlorite. A possible explanation is given, in terms of an unusual competition between the epoxidation and the O-dealkylation of the OCH2O moiety.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5197c8d74c4947de75f0f924b111e9f1 https://doi.org/10.1016/0040-4039(95)02312-7 Zobrazit plný text záznamu Full Text from ScienceDirect