Magnetic, structural, and Raman characterization ofRBa2Cu2NbO8(R=Pr, La, or Nd)

Autor: C. A. Smith, M. Bennahmias, R.N. Shelton, T.J. Goodwin, Peter Klavins, Harry B. Radousky, J.M. Link, J.C. O'Brien
Rok vydání: 1992
Předmět:
Zdroj: Physical Review B. 46:11986-11992
ISSN: 1095-3795
0163-1829
DOI: 10.1103/physrevb.46.11986
Popis: ${\mathrm{PrBa}}_{2}$${\mathrm{Cu}}_{2}$${\mathrm{NbO}}_{8}$ (PrBCNO) is an insulator analogous to the ${\mathrm{PrBa}}_{2}$${\mathrm{Cu}}_{3}$${\mathrm{O}}_{7}$ system having a similar structure but with ${\mathrm{NbO}}_{2}$ planes replacing the CuO chains. Single-phase polycrystalline samples of RBCNO have been synthesized with R=La, Pr, or Nd. These materials were characterized using magnetization, thermal gravimetric analysis in different atmospheres, x-ray diffraction, and Raman spectroscopy. The PrBCNO samples show a signature in the magnetization of a magnetic ordering at 12 K. No such magnetic phase transition is observed down to 2 K in ${\mathrm{NdBa}}_{2}$${\mathrm{Cu}}_{2}$${\mathrm{NbO}}_{8}$.
Databáze: OpenAIRE