Macro-N-heterocyclic compounds: X-ray photoelectron spectra and structure

Autor: M. I. Bazanov, E. S. Yurina, A. V. Petrov, T. M. Ivanova
Rok vydání: 2006
Předmět:
Zdroj: Russian Journal of Coordination Chemistry. 32:71-74
ISSN: 1608-3318
1070-3284
Popis: Bi-, tri-, and tetradentate macroheterocylic ligands, i.e., structural analogs of phthalocyanine, are studied by X-ray photoelectron spectroscopy. The X-ray photoelectron spectra of N1s lines of the nitrogen atoms of these compounds are analyzed. The binding energies and integrated intensities of N1s lines of the nitrogen atoms are determined and the effective charges on the nitrogen atoms are calculated. The structures of bi-, tri-and tetradentate macroheterocyclic ligands containing isoindole, benzene, and pyridine fragments are established on the basis of the data obtained.
Databáze: OpenAIRE