Hydrolysis of radicals and molecules of ethers

Autor:	V. S. Kosobutskii
Rok vydání:	2017
Předmět:	Hydrolysis constant chemistry.chemical_compound Hydrolysis Aqueous solution Reaction rate constant chemistry Radical Yield (chemistry) Radiolysis Organic chemistry Ether General Chemistry
Zdroj:	Russian Journal of General Chemistry. 87:1481-1485
ISSN:	1608-3350 1070-3632
DOI:	10.1134/s1070363217070064
Popis:	Radiolysis of aqueous solutions of diisopropyl and methyl tert-butyl ethers under γ-irradiation has been studied. The effect of pH on the products yield has been investigated. It has been shown that the rate constants of ether radicals hydrolysis are ~109 times higher than these of ether molecules in acidic as well as basic medium.
Databáze:	OpenAIRE
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