Synthesis, Characterization, Spectral Studies, and Antifungal Activity of Mn(II), Fe(II), Co(II), Ni(II), Cu(II), and Zn(II) Complexes with 2‐Hydroxy‐1‐(1‐hydroxy‐2‐naphthylazo)‐6‐nitronaphthalene‐4‐sulfonic Acid Sodium Salt
| Autor: | Gajanan Pandey, Krishan K. Narang |
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| Rok vydání: | 2004 |
| Předmět: |
chemistry.chemical_classification
Alternaria brassicicola biology Stereochemistry Ligand Aspergillus niger Aspergillus flavus Sulfonic acid biology.organism_classification Alternaria brassicae Inorganic Chemistry Eriochrome Black T chemistry.chemical_compound chemistry Physical and Theoretical Chemistry Solubility Nuclear chemistry |
| Zdroj: | Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 34:397-415 |
| ISSN: | 1532-2440 0094-5714 |
| DOI: | 10.1081/sim-120028309 |
| Popis: | Mn(II), Fe(II), Co(II), Ni(II), Cu(II), and Zn(II), complexes of the type Na2[M(HL)2(H2O)2] of the ligand 2‐hydroxy‐1‐(1‐hydroxy‐2‐naphthylazo)‐6‐nitronaphthalene‐4‐sulfonic acid sodium salt (Eriochrome Black T, NaH2L), have been synthesized and characterized by various physico‐chemical (elemental analyzes, solubility, electrolytic conductances and magnetic susceptibility measurements) and spectral (UV‐Visible spectra, IR spectra, ESR spectra, and powder x‐ray diffraction) techniques for the structure determination and the antifungal activity was measured against 10 fungi. The data suggest 1:2 (M:L) compositions with octahedral geometries around M(II), except for Cu(II), very significant antifungal activity against Alternaria brassicicola and Alternaria brassicae and moderate activity against the fungi Alternaria solanae, Curvularia species, Curvularia lunata, Helminthosporium oryzae, Collectotrichum capsici, Aspergillus niger, Aspergillus flavus, and Fusarium udum. |
| Databáze: | OpenAIRE |
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