Structures of palladium(II) and nickel(II) complexes of the mesocyclic diphosphine, cis-1,5-diphenyl-1,5-diphosphacyclooctane

Autor:	Brian W. Arbuckle, W. Kenneth Musker
Rok vydání:	1991
Předmět:	Stereochemistry chemistry.chemical_element Crystal structure Medicinal chemistry Chloride Inorganic Chemistry Nickel chemistry X-ray crystallography Materials Chemistry medicine Molecule Physical and Theoretical Chemistry Monoclinic crystal system Palladium medicine.drug
Zdroj:	Polyhedron. 10:415-419
ISSN:	0277-5387
DOI:	10.1016/s0277-5387(00)80205-3
Popis:	The preparation and X-ray crystal structures of a planar mono complex of cis- 1,5-diphenyl-1,5-diphosphacyclooctane with palladium(II) chloride and a pentacoordinated bis complex with nickel(II) chloride are reported. Dichloro(1,5-diphenyl-1,5-diphos- phacyclooctane)palladium(II) crystallizes in the monoclinic space group C2/c with cell constants a = 26.647(6), b = 7.884(1), c = 13,053(3) A, β = 98.15(2)° and Z = 4 at T = 130 K. Chloro-bis(1,5-diphenyl-1,5-diphosphacyclooctane)nickel(II) chloride crystallizes in the monoclinic space group P21/n with a = 18.178(7), b = 10.225(2), c = 20.959(7) A, β = 111.77(2)° and Z = 4 at T = 130 K.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::51781efd18a777d304a290ebb9e106c8 https://doi.org/10.1016/s0277-5387(00)80205-3 Zobrazit plný text záznamu