Silicon-containing alka-1,3-dienes and their functional derivatives in organic synthesis

Autor:	T I Voropaeva, M D Stadnichuk
Rok vydání:	1995
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Addition reaction Nucleophilic addition chemistry Organic reaction Double bond Reagent Organic chemistry Organic synthesis General Chemistry Protecting group Chemical reaction
Zdroj:	Russian Chemical Reviews. 64:25-46
ISSN:	1468-4837 0036-021X
DOI:	10.1070/rc1995v064n01abeh000135
Popis:	Data on the synthesis and chemical reactions of silicon-containing 1,3-dienes are surveyed for the first time in the present review. It is shown that the addition reactions of 1- and 2-triorganosilylalka-1,3-dienes and their derivatives are the most interesting and promising in fine organic synthesis. The application of the trialkylsilyl group as a protecting group and as a new reaction centre, which makes it possible to obtain carbon–carbon or carbon–heteroatom bonds, is examined. It has been found that the double bonds remote from the silicon atom are the most reactive in addition reactions and that regardless of the nature of the reagent the attacking species always binds to the terminal carbon atom of the buta-1,3-diene fragment. The bibliography includes 329 references.
Databáze:	OpenAIRE
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