Effect of the nature of the solvent on the interaction of polyamic acids of various chemical structure with poly-N-vinylpyrrolidone

Autor:	T. N. Nekrasova, Ye.V. Anufriyeva, S. A. Dauengauer, M.S. Romanova, Lushchik Vanda B, Yu. N. Sazanov, M.M. Koton, T.V. Sheveleva, T. N. Spirina
Rok vydání:	1988
Předmět:	chemistry.chemical_classification Chemistry Hydrogen bond Chemical structure General Engineering Polymer Solvent chemistry.chemical_compound Amide Polymer chemistry Polyamide Organic chemistry Molecule Macromolecule
Zdroj:	Polymer Science U.S.S.R.. 30:1773-1778
ISSN:	0032-3950
DOI:	10.1016/0032-3950(88)90402-9
Popis:	The interaction of polyamic acids of various chemical structure with poly-N-vinylpyrrolidone in amide solvents and in methanol is studied by a polarized luminescence method. The formation of interpolymer complexes from aromatic amide-containing and aliphatic vinyl amide-containing polymers depends primarily on the parameters of interaction of the amide solvent molecules with the macromolecules, which depend on the chemical structure features of the polymer. Hydrogen bonds between the COOH groups of the polyamide acids and the C = O groups of the poly-N-vinylpyrrolidone play an essential part in stabilizing the complexes. The role of crown-rings in polyamide acid chains in the formation of interpolymer contacts with poly-N-vinylpyrrolidone is discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::514381bde5711cbdedaba0c8061e05d5 https://doi.org/10.1016/0032-3950(88)90402-9 Zobrazit plný text záznamu